SOLUTION —
Given : pair of equation is $k x+2 y=3$
$3 x+6 y=10$
For a unique solution, $\frac{a_1}{a_2} \neq \frac{b_1}{b_2}$
Here, $a_1=k, b_1=2$
$a_2=3, b=6$
$\begin{aligned}\frac{k}{3} & \neq \frac{2}{6} \\k & \neq 1\end{aligned}$
Hence, the pair of equation has a unique solution for all real values of $k$ except 1.