The arrangement of elements in Mendeleev's Periodic Table and the Modern Periodic Table has several key differences and similarities. Here's a comparison and contrast of the two:
Mendeleev's Periodic Table
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Basis of Arrangement:
- Mendeleev arranged elements in order of increasing atomic mass.
- He left gaps for undiscovered elements and predicted their properties.
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Periodicity:
- Mendeleev's table showed periodicity (repeating patterns) in the properties of elements.
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Grouping:
- Elements with similar properties were placed in the same column (group).
- Some elements were placed out of strict atomic mass order to group elements with similar properties together.
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Gaps for New Elements:
- Mendeleev intentionally left gaps for elements he predicted would be discovered (e.g., gallium, germanium).
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Unknown Noble Gases:
- Noble gases were not included in Mendeleev's table as they had not been discovered yet.
Modern Periodic Table
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Basis of Arrangement:
- The modern periodic table arranges elements in order of increasing atomic number (number of protons).
- This arrangement resolves inconsistencies that appeared in Mendeleev's table when elements were ordered by atomic mass.
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Periodicity:
- The modern table also exhibits periodicity, with elements showing repeating patterns in properties.
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Grouping:
- Elements are grouped into columns (groups) based on their similar valence electron configurations, leading to similar chemical properties.
- Groups are numbered 1 through 18.
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Periods:
- Elements are arranged in rows (periods) corresponding to the number of electron shells.
- There are 7 periods in the modern table.
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Inclusion of Noble Gases:
- Noble gases are included in Group 18, completing the periodic table.
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Lanthanides and Actinides:
- These are placed separately below the main body of the periodic table to maintain its structure.
Key Differences
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Atomic Mass vs. Atomic Number:
- Mendeleev used atomic mass as the basis for arrangement, while the modern table uses atomic number.
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Placement of Elements:
- Mendeleev's arrangement sometimes placed elements with slightly incorrect masses in positions to align with their properties, whereas the modern table's use of atomic numbers avoids this issue.
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Gaps for New Elements:
- Mendeleev's table had gaps for undiscovered elements, which were later filled as elements were discovered.
- The modern table is complete, with no gaps.
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Noble Gases:
- Mendeleev's table did not include noble gases, whereas the modern table does.
Key Similarities
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Periodicity:
- Both tables demonstrate periodicity in the properties of elements.
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Grouping by Properties:
- Both tables group elements with similar properties into the same columns (groups).
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Predictive Power:
- Both tables have been useful in predicting the properties of elements based on their position.
In summary, while Mendeleev's periodic table was a groundbreaking step in understanding the arrangement of elements and their properties, the modern periodic table, with its basis on atomic number, provides a more accurate and consistent framework.