Why is purest monomer used in free radical polymerisation always?

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For a saturated solution of AgCl at $25^{\circ} C, k =3.4 \times 10^{-6} ohm ^{-1} cm ^{-1}$ and that of $H _{2} O (\ell)$ used is $2.02 \times 10^{-6} ohm ^{-1} cm ^{-1}$.

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