1.5276g of CdCl2 was found to contain 0.9367g of cadmium. Calculate the atomic weight of cadmium.
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1.5276g of CdCl2 was found to contain 0.9367g of cadmium. Calculate the atomic weight of cadmium.

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SOLUTION : Wt. of $C d C l_{2}=1.5276 g$ and wt. of $C d=0.9367 g$

$\therefore \quad$ Wt. of chlorine $=(1.5276-0.9367) g =0.5909 g$

We know that

$\text { eq. wt. }=\frac{\text { wt. of } C d}{\text { wt. of chlorine }} \times 35 \cdot 5=\frac{0 \cdot 9367 \times 35 \cdot 5}{0.5909}=56 \cdot 275$

Hence equivalent weight of cadmium $=56 \cdot 275$

$\begin{array}{ll}\because \quad \text { Atomic weight } \quad=\text { equivalent weight } \times \text { valency } \\\therefore \quad \text { Atomic weight } \quad=56 \cdot 275 \times 2=112 \cdot 550 . \\\quad\left(\because \text { Valency of } C d=2, \text { from } C d C l_{2}\right)\end{array}$

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