SOLUTION —
Let equation of line passing, through $(0,0)$ be $y-m x=0$ and it is a tangent to the circle $(x-7)^2+(y+1)^2=25$, if
$\frac{-1-7 m}{\sqrt{1+m^2}}=5 \Rightarrow m=\frac{3}{4},-\frac{4}{3}$
Now, $\frac{3}{4} \times\left(-\frac{4}{3}\right)=-1$
Hence, angle between tangents is $\frac{\pi}{2}$
So, The correct option of this question will be (D).