The dissociation energy of H2 is 430.53 kJ mol^-1. If hydrogen is dissociated by illumination with radiation of wavelength 253.7 nm, the fraction of the radiant energy which will be converted into kinetic energy is given by
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The dissociation energy of $\mathrm{H}_2$ is $430.53 \mathrm{~kJ} \mathrm{~mol}^{-1}$. If hydrogen is dissociated by illumination with radiation of wavelength $253.7 \mathrm{~nm}$, the fraction of the radiant energy which will be converted into kinetic energy is given by

(A) $100 \%$

(B) $8.78 \%$

(C) $2.22 \%$

(D) $1.22 \%$

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SOLUTION —

Energy of 1 mole of photons,

$E=N_0 h v=\frac{N_0 \times h \times c}{\lambda}$

Energy converted into $K . E .=(472-430.53) \mathrm{kJ}$ $\%$ of energy converted into K.E.

$=\frac{(472-430.53)}{472} \times 100=8.78 \%$

So, The correct option of this question will be (B).

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