SOLUTION —
Since, $\mathbf{a}, \mathbf{b}$ and $\mathbf{c}$ are unit vectors and $\mathbf{a}+\mathbf{b}+\mathbf{c}=\mathbf{0}$. It means they are along sides of an equilateral triangle.
$\theta=\pi-\frac{\pi}{3}=\frac{2 \pi}{3}$
So, The correct option of this question will be (B).